Take a look at Absolute Beginner’s Video Series in MSDN.
http://msdn.microsoft.com/vstudio/express/visualcsharp/learning/default.aspx
When I watched videos and taked a look at samples I learned very much
about using Visual C# Express Edition and programming with it. This is
C# stuff. The series includes over 10 hours of videos.
Lessons
Lesson 1: Getting Started with Visual C# 2005 Express Edition
Lesson 2: Creating a Windows Application User Interface
Lesson 3: Writing Code to Handle Events and Set Properties
Lesson 4: Working with Variables, Expressions, Statements, and Operators
Lesson 5: Using Branching and Recursion
Lesson 6: Object Oriented Programming Fundamentals
Lesson 7: Getting to Know the .NET Framework
Lesson 8: Obtaining Data from a SQL Server 2005 Express Edition Database
Lesson 9: Databinding Data to User Interface Controls
Lesson 10: Working with XML
Lesson 11: Handling Exceptions
Lesson 12: The RSS Reader Project - Designing and Planning
Lesson 13: The RSS Reader Project - Building the UI
Lesson 14: The RSS Reader Project - Working with XML and SQL Server 2005 Express Edition Data
Lesson 15: The RSS Reader Project - Expanding and Refining Application Functionality
Lesson 16: The RSS Reader Project - Fortifying, Testing and Deploying the Application
Regards!
Timo

Great tip!
djackowski
The link to the Absolute Beginner's videos on my VSExpress Start page changed to: http://msdn.microsoft.com/vstudio/express/default.aspx, so I was glad to find your post with the correct URL. I hope that was just an error on the redirect from go.microsoft.com...
Anyway, Thanks!
DanC#